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Accessibility information
Author(s):   Tsang, W.
Title:   Single pulse shock tube study on the thermal stability of ketones
Journal:   Int. J. Chem. Kinet.
Volume:   16
Year:   1984
Reference type:   Journal article
Squib:   1984TSA1543

Reaction:   n-C4H9COCH3(CH3)2CO + CH3CH=CH2
Reaction order:   1
Temperature:   1020 - 1180 K
Pressure:  1.52 - 6.08 bar
Rate expression:   1.91x1013 [s-1] e-269389 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1020 3.06E-1
1025 3.57E-1
1050 7.58E-1
1075 1.55E0
1100 3.08E0
1125 5.93E0
1150 1.11E1
1175 2.02E1
1180 2.27E1