Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tully, F.P.
Title:   Elementary Combustion Reactions. Laser photolysis-laser-induced fluorescence kinetic studies
Volume:   249
Page(s):   226 - 237
Year:   1984
Book Title:   The Chemistry of Combustion Processes
Publisher address:   ACS Symp. Ser., Ed. T.M. Sloane, Washington, DC.
Reference type:   Book Chapter
Squib:   1984TUL226-237C

Reaction:   C2H4 + ·OH → Products
Reaction order:   2
Temperature:   291 - 796 K
Pressure:  0.80 bar
Rate expression:   1.74x10-12 [±1.21x10-13 cm3/molecule s] e3833 [±8314472 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
291 8.50E-12
300 8.11E-12
350 6.51E-12
400 5.52E-12
450 4.86E-12
500 4.38E-12
550 4.03E-12
600 3.76E-12
650 3.54E-12
700 3.37E-12
750 3.22E-12
796 3.11E-12