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Accessibility information
Author(s):   Vohringer, C.M. de; Staricco, E.H.
Title:   Gas phase reactions of CF3, C2F5, and n-C3F7 with carbon tetrachloride
Journal:   Int. J. Chem. Kinet.
Volume:   16
Year:   1984
Reference type:   Journal article
Squib:   1984VOH/STA1351

Reaction:   CCl4 + ·CF3CF3Cl + ·CCl3
Reaction order:   2
Reference reaction:   ·CF3 + ·CF3C2F6
Temperature:   360 - 500 K
Pressure:  0.11 - 0.15 bar
Rate expression:   1.05x10-11 [cm3/molecule s] e-47309 [J/mole]/RT
Bath gas:   CF3I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
360 1.43E-18
375 2.70E-18
400 6.96E-18
425 1.61E-17
450 3.38E-17
475 6.57E-17
500 1.20E-16