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Accessibility information
Author(s):   Weissman, M.; Benson, S.W.
Title:   Pyrolysis of methyl chloride, a pathway in the chlorine-catalyzed polymerization of methane
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   307 - 333
Year:   1984
Reference type:   Journal article
Squib:   1984WEI/BEN307-333

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1984WEI/BEN307-333   Benzene + Phenyl → Adduct  1260 - 1310   2.09E-12       4.52E04      2
  1984WEI/BEN307-333   Benzene + C2H3 → Adduct  1260 - 1310   2.62E-13       1.26E04      2
  1984WEI/BEN307-333   C2H4 + C2H3CH2=CHCH2CH2·  1260 - 1310   3.32E-13       8398      2
  1984WEI/BEN307-333   C2H4 + ·ClC2H3 + HCl  1260 - 1310   1.66E-10       2.93E04      2
  1984WEI/BEN307-333   C2H2 + C2H3 → CH2=CHCH=CH·  1260 - 1310   1.05E-12       1.96E04      2
  1984WEI/BEN307-333   C2H2 + ·Cl·C2H + HCl  1260 - 1310   2.62E-10       7.07E04      2
  1984WEI/BEN307-333   C2H2 + CH2=CHCH=CH· → Adduct  1260 - 1310   6.61E-12       2.89E04      2
  1984WEI/BEN307-333   CH3Cl·CH3 + ·Cl  1260 - 1310   2.50E15       3.49E05      1
  1984WEI/BEN307-333   1,3-Butadiene + C2H3 → Adduct  1260 - 1310   5.25E-13       1.26E04      2
  1984WEI/BEN307-333   Vinylacetylene + ·Cl → HCCCHCH· + HCl  1260 - 1310   1.66E-10       4182      2
  1984WEI/BEN307-333   1-C3H7CH3CH=CH2 +   1260 - 1310   6.31E13       1.59E05      1
  1984WEI/BEN307-333   CH2=CHCH2CH2·1,3-Butadiene +   1260 - 1310   3.16E13       1.46E05      1
  1984WEI/BEN307-333   ·CH3 + ·CH2ClC2H5Cl  1260 - 1310   8.32E-11              2
  1984WEI/BEN307-333   C2H3C2H2 +   1260 - 1310   1.00E11       1.69E05      1
  1984WEI/BEN307-333   HCCCHCH· → 1,3-Butadiyne +   1260 - 1310   1.00E14       1.70E05      1
  1984WEI/BEN307-333   iso-C4H9iso-C4H8 +   1260 - 1310   1.00E14       1.52E05      1
  1984WEI/BEN307-333   ·CH2Cl + ·CH2ClCH2ClCH2Cl  1260 - 1310   1.66E-11              2
  1984WEI/BEN307-333   HCl + CH2=CHCH=CH· → 1,3-Butadiene + ·Cl  1260 - 1310   1.32E-11       4182      2
  1984WEI/BEN307-333   CH2=CHCH=CH· → Vinylacetylene +   1260 - 1310   1.00E14       1.73E05      1

Search returned 19 records.