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Author(s):   Brouwer, L.; Muller-Markgraf, W.; Troe, J.
Title:   Identification of primary reaction products in the thermal decomposition of aromatic hydrocarbons
Journal:   Symp. Int. Combust. Proc.
Volume:   20
Year:   1985
Reference type:   Journal article
Squib:   1985BRO/MUL799

Reaction:   1,4-Dimethylbenzene4-Methylbenzyl +
Reaction order:   1
Temperature:   1400 - 1800 K
Pressure:  24.26 bar
Rate expression:   3.98x1015 [s-1] e-354197 [±14135 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 2.43E2
1425 4.14E2
1450 6.93E2
1475 1.14E3
1500 1.84E3
1525 2.94E3
1550 4.61E3
1575 7.13E3
1600 1.09E4
1625 1.64E4
1650 2.44E4
1675 3.59E4
1700 5.21E4
1725 7.49E4
1750 1.07E5
1775 1.50E5
1800 2.10E5