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Accessibility information
Author(s):   Crespo, M.T.; Figuera, J.M.; Menendez, V.
Title:   An estimation of the high pressure limit rate constant for the radical scission of the C-Br bond in the vinyl bromide
Journal:   An. Quim. Ser. A
Volume:   81
Year:   1985
Reference type:   Journal article
Squib:   1985CRE/FIG391

Reaction:   CH2=CHBrC2H3 + Br·
Reaction order:   1
Temperature:   300 - 450 K
Rate expression:   2.05x1013 [±4.7x1012 s-1] e-288512 [±5779 J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.20E-37
325 8.76E-34
350 1.80E-30
375 1.33E-27
400 4.33E-25
425 7.13E-23
450 6.65E-21