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Accessibility information
Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   n-C4H10n-C4H9 +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   1.58x1016 [s-1] e-409903 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 6.75E-56
400 4.70E-38
500 2.38E-27
600 3.27E-20
700 4.09E-15
800 2.72E-11
900 2.56E-8
1000 6.14E-6
1100 5.42E-4
1200 2.27E-2
1300 5.36E-1
1400 8.04E0
1500 8.41E1
1600 6.56E2
1700 4.02E3
1800 2.01E4
1900 8.51E4
2000 3.11E5
2100 1.01E6
2200 2.93E6
2300 7.76E6
2400 1.89E7
2500 4.31E7