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Title: Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal: J. Phys. Chem.
Volume: 89
Page(s): 4600 - 4608
Year: 1985
Reference type: Journal article
Squib: 1985DEA4600-4608
Reaction:
n-C4H10 → n-C3H7 + ·CH3
Reaction order:
1
Temperature:
300 - 2500
K
Rate expression:
1.0x1017 [s-1] e-354197 [J/mole]/RT
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 300 | 2.14E-45 |
| 400 | 5.59E-30 |
| 500 | 9.96E-21 |
| 600 | 1.46E-14 |
| 700 | 3.72E-10 |
| 800 | 7.48E-7 |
| 900 | 2.78E-4 |
| 1000 | 3.16E-2 |
| 1100 | 1.52E0 |
| 1200 | 3.82E1 |
| 1300 | 5.87E2 |
| 1400 | 6.10E3 |
| 1500 | 4.63E4 |
| 1600 | 2.73E5 |
| 1700 | 1.31E6 |
| 1800 | 5.27E6 |
| 1900 | 1.83E7 |
| 2000 | 5.62E7 |
| 2100 | 1.55E8 |
| 2200 | 3.89E8 |
| 2300 | 9.04E8 |
| 2400 | 1.96E9 |
| 2500 | 3.98E9 |