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Accessibility information
Author(s):   Dean, A.M.
Title:   Predictions of pressure and temperature effects upon radical addition and recombination reactions
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4600 - 4608
Year:   1985
Reference type:   Journal article
Squib:   1985DEA4600-4608

Reaction:   n-C4H10n-C3H7 + ·CH3
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   1.0x1017 [s-1] e-354197 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 2.14E-45
400 5.59E-30
500 9.96E-21
600 1.46E-14
700 3.72E-10
800 7.48E-7
900 2.78E-4
1000 3.16E-2
1100 1.52E0
1200 3.82E1
1300 5.87E2
1400 6.10E3
1500 4.63E4
1600 2.73E5
1700 1.31E6
1800 5.27E6
1900 1.83E7
2000 5.62E7
2100 1.55E8
2200 3.89E8
2300 9.04E8
2400 1.96E9
2500 3.98E9