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Accessibility information
Author(s):   Gonzalez, A.C.; Larson, C.W.; McMillen, D.F.; Golden, D.M.
Title:   Mechanism of decomposition of nitroaromatics. Laser-powered homogeneous pyrolysis of substituted nitrobenzenes
Journal:   J. Phys. Chem.
Volume:   89
Page(s):  
Year:   1985
Reference type:   Journal article
Squib:   1985GON/LAR4809

Reaction:   Benzene, 1-methyl-4-nitro- → Phenyl, 4-methyl- + NO2
Reaction order:   1
Reference reaction:   CyclohexeneC2H4 + 1,3-Butadiene
Temperature:   1110 - 1250 K
Pressure:  0.15 bar
Rate expression:   7.94x1014 [s-1] e-285186 [±8564 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   SF6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1110 3.02E1
1125 4.56E1
1150 8.84E1
1175 1.67E2
1200 3.06E2
1225 5.49E2
1250 9.61E2