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Author(s):   Husain, D.; Plane, J.M.C.; Xiang, C.C.
Title:   Absolute rate data for Rb + OH + He determined by time-resolved molecular resonance-fluoroescence spectroscopy, OH(A2Σ - X2π), coupled with steady atomic resonance-fluoroescence measurements, Rb(62PJ - 52S1/2)
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   81
Year:   1985
Reference type:   Journal article
Squib:   1985HUS/PLA561

Reaction:   ·OH + KKOH
Reaction order:   3
Temperature:   490 - 2000 K
Pressure:  2.67E-2 - 9.33E-2 bar
Rate expression:   2.19x10-30 [±5.79x10-31 cm6/molecule2 s] (T/298 K)-1.55
Bath gas:   He
Category:  Theory
Data type:   Other theoretical

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
490 1.01E-30
500 9.82E-31
600 7.40E-31
700 5.83E-31
800 4.74E-31
900 3.95E-31
1000 3.35E-31
1100 2.89E-31
1200 2.53E-31
1300 2.23E-31
1400 1.99E-31
1500 1.79E-31
1600 1.62E-31
1700 1.47E-31
1800 1.35E-31
1900 1.24E-31
2000 1.14E-31