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Accessibility information
Author(s):   Kerr, J.A.; Wright, J.P.
Title:   Kinetic study of the gas-phase decomposition of the trifluoroacetyl radical
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   81
Year:   1985
Reference type:   Journal article
Squib:   1985KER/WRI1471

Reaction:   CF3C(O)CO + ·CF3
Reaction order:   1
Temperature:   338 - 417 K
Pressure:  6.67E-2 - 0.99 bar
Rate expression:   2.19x1013 [s-1] e-41822 [±4182 J/mole]/RT
Uncertainty:   2.0
Bath gas:   SF6
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
338 7.54E6
350 1.26E7
375 3.27E7
400 7.57E7
417 1.26E8