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Accessibility information
Author(s):   Zabarnick, S.; Heicklen, J.
Title:   Reactions of alkoxy radicals with O2. III. i-C4H9O radicals
Journal:   Int. J. Chem. Kinet.
Volume:   17
Year:   1985
Reference type:   Journal article
Squib:   1985ZAB/HEI503

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1985ZAB/HEI503   (CH3)2CHCH2ONO + ·OHHNO2 + (CH3)2CHCH2  265 - 361   0.66           0.66  2
  Reference reaction:  (CH3)2CHCH2ONO + ·OH → Products 2
  1985ZAB/HEI503   O2 + (CH3)2CHCH2O· → (CH3)2CHCHO + HO2  265 - 361   3.20E-13       6951   1.94E-14  2
  1985ZAB/HEI503   O2 + (CH3)2CHCH2O· → (CH3)2CHCHO + HO2  265 - 361   7.08E-03       66.52   6.89E-03  2
  Reference reaction:  NO + (CH3)2CHCH2O· → Products 2
  1985ZAB/HEI503   (CH3)2CHCH2O· → CH2O + iso-C3H7  328 - 361   1.94E20       1.09E04      1
  Reference reaction:  O2 + (CH3)2CHCH2O· → (CH3)2CHCHO + HO2 2
  1985ZAB/HEI503   (CH3)2CHCH2O· → CH2O + iso-C3H7  296 - 361   4.52E20       3.48E04   3.54E14  1
  Reference reaction:  NO + (CH3)2CHCH2O· → Products 2

Search returned 5 records.