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Accessibility information
Author(s):   Zabarnick, S.; Heicklen, J.
Title:   Reactions of alkoxy radicals with O2. III. i-C4H9O radicals
Journal:   Int. J. Chem. Kinet.
Volume:   17
Page(s):  
Year:   1985
Reference type:   Journal article
Squib:   1985ZAB/HEI503

Reaction:   (CH3)2CHCH2O → CH2O + iso-C3H7
Reaction order:   1
Reference reaction:   O2 + (CH3)2CHCH2O → (CH3)2CHCHO + HO2
Reference reaction order:   2
Temperature:   328 - 361 K
Pressure:  0.20 bar
Rate expression:   1.94x1020 [molecule/cm3] e-10892 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
328 3.57E18
350 4.59E18
361 5.15E18