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Accessibility information
Author(s):   Atkinson, R.
Title:   Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions
Journal:   Chem. Rev.
Volume:   86
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986ATK69

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1986ATK69   CH2O + ·OHHCO + H2O  228 - 426   9.00E-12           9.00E-12  2
  1986ATK69   C2H5OH + ·OH → Other Products + H2O  298 - 625   5.28E-12       1463   2.93E-12  2
  1986ATK69   CH3OH + ·OH → Other Products + H2O  298 - 420   1.34E-11       6693   8.99E-13  2
  1986ATK69   Acetone + ·OH → Products  300   2.31E-13              2
  1986ATK69   CHCl3 + ·OH·CCl3 + H2O  240 - 500   5.60E-13   2.00   4190   1.03E-13  2
  1986ATK69   Benzene + ·OH → Products  250 - 325   7.57E-12       4398   1.28E-12  2
  1986ATK69   Benzene + ·OH → Products  450 - 1000   2.89E-13   2.00   2860      2
  1986ATK69   CH3CCl3 + ·OHH2O + CCl3CH2  250 - 420   5.26E-13   2.00   9395   1.19E-14  2
  1986ATK69   CH4 + ·OH·CH3 + H2O  238 - 1250   6.18E-13   2.00   1.06E04   8.42E-15  2
  1986ATK69   CH3Br + ·OHH2O + ·CH2Br  240 - 350   7.41E-13       7275   3.93E-14  2
  1986ATK69   CH3Br + ·OHH2O + ·CH2Br  240 - 350   1.04E-13   2.00   2461   3.86E-14  2
  1986ATK69   C2H6 + ·OH·C2H5 + H2O  238 - 850   1.22E-12   2.00   3692   2.75E-13  2
  1986ATK69   C2H4 + ·OH → Products  290 - 500   2.14E-12       -3417   8.51E-12  2
  1986ATK69   C2H2 + ·OH → Products  270 - 420   1.69E-12       1937   7.75E-13  2
  1986ATK69   C2H2 + ·OH → Products  270 - 420   1.91E-12       1937   8.74E-13  2
  1986ATK69   C2H2 + ·OH → Products  298   4.00E-30           4.00E-30  3
  1986ATK69   CH3Cl + ·OH·CH2Cl + H2O  250 - 500   3.11E-13   2.00   4864   4.36E-14  2
  1986ATK69   CH3SH + ·OH → Products  240 - 420   9.71E-12       -3043   3.32E-11  2
  1986ATK69   C3H8 + ·OH → Other Products + H2O  250 - 850   1.13E-12   2.00   -116   1.19E-12  2
  1986ATK69   C2H5Cl + ·OH → Other Products + H2O  298   4.00E-13           4.00E-13  2
  1986ATK69   CH3CN + ·OH → Products  250 - 433   6.77E-13       8647   2.07E-14  2
  1986ATK69   CH3CHO + ·OH → Products  298 - 426   6.87E-12       -2129   1.62E-11  2
  1986ATK69   C2H5SH + ·OH → Products  250 - 420   1.23E-11       -3293   4.65E-11  2
  1986ATK69   CH2Cl2 + ·OHCHCl2 + H2O  250 - 500   7.54E-13   2.00   4157   1.41E-13  2
  1986ATK69   CH2F2 + ·OH·CHF2 + H2O  250 - 500   4.48E-13   2.00   9229   1.08E-14  2
  1986ATK69   (CH3)2S + ·OHH2O + CH3SCH2  250 - 420   6.77E-12       1139   4.28E-12  2
  1986ATK69   iso-C4H10 + ·OH → Other Products + H2O  250 - 900   8.52E-13   2.00   -2536   2.37E-12  2
  1986ATK69   CH3CHF2 + ·OH → Other Products + H2O  295   3.40E-14              2
  1986ATK69   CHFCl2 + ·OH·CCl2F + H2O  240 - 500   1.51E-13   2.00   3983   3.03E-14  2
  1986ATK69   CHF2Cl + ·OH·CClF2 + H2O  250 - 500   1.34E-13   2.00   8314   4.67E-15  2
  1986ATK69   CHF3 + ·OH·CF3 + H2O  290 - 500   1.86E-13   2.00   1.70E04   1.91E-16  2
  1986ATK69   CH3CF2Cl + ·OH → CF2ClCH2· + H2O  270 - 420   1.83E-13   2.00   9728   3.60E-15  2
  1986ATK69   CF3CH2Cl + ·OHH2O + CF3CHCl  280 - 420   7.56E-14   2.00   3808   1.62E-14  2
  1986ATK69   iso-C5H12 + ·OH → Other Products + H2O  298   3.90E-12           3.90E-12  2
  1986ATK69   CH2=C(CH3)CH=CH2 + ·OH → Products  290 - 422   2.54E-11       -3401   1.00E-10  2
  1986ATK69   Methacrolein + ·OH → Products  298 - 424   1.96E-11       -1114   3.07E-11  2
  1986ATK69   C2H5COCH3 + ·OH → Products  300   1.00E-12              2
  1986ATK69   CH2=CHCOCH3 + ·OH → Products  290 - 420   3.29E-12       -4274   1.85E-11  2
  1986ATK69   CHCl2CH2Cl + ·OH → Other Products + H2O  280 - 420   1.66E-12       4016   3.28E-13  2
  1986ATK69   CHCl2CH2Cl + ·OH → Other Products + H2O  280 - 420   1.57E-13   2.00   -1821   3.28E-13  2
  1986ATK69   C2HCl3 + ·OH → Products  234 - 420   5.63E-13       -3550   2.36E-12  2
  1986ATK69   (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O  298 - 500   6.19E-12           6.19E-12  2
  1986ATK69   alpha-pinene + ·OH → Products  298 - 422   1.20E-11       -3692   5.33E-11  2
  1986ATK69   Naphthalene + ·OH → Products  298 - 410   1.05E-12       -7500   2.17E-11  2
  1986ATK69   Naphthalene + ·OH → Products  600 - 1000   9.96E-13   2.00   8057      2
  1986ATK69   Biphenyl + ·OH → Products  298   7.01E-12           7.01E-12  2
  1986ATK69   1,2-Dimethylbenzene + ·OH → Products  298 - 320   1.47E-11           1.47E-11  2
  1986ATK69   1,2-Dimethylbenzene + ·OH → Products  450 - 1000   1.55E-12   2.00   291      2
  1986ATK69   2-Methylphenol + ·OH → Products  300   4.00E-11              2
  1986ATK69   (C2H5)2CHCH3 + ·OH → Other Products + H2O  298   5.60E-12           5.60E-12  2
  1986ATK69   Ethylbenzene + ·OH → Products  298   7.51E-12           7.51E-12  2
  1986ATK69   Benzaldehyde + ·OH → Products  298   1.30E-11           1.30E-11  2
  1986ATK69   1-Phenylpropane + ·OH → Products  298   5.71E-12           5.71E-12  2
  1986ATK69   1,4-Dimethylbenzene + ·OH → Products  297 - 320   1.52E-11           1.52E-11  2
  1986ATK69   1,4-Dimethylbenzene + ·OH → Products  450 - 1000   1.55E-12   2.00   823      2
  1986ATK69   4-Methylphenol + ·OH → Products  300   4.40E-11              2
  1986ATK69   1-C4H10 + ·OH → Other Products + H2O  250 - 500   1.55E-11       4490   2.53E-12  2
  1986ATK69   1-C4H8 + ·OH → Products  280 - 420   6.54E-12       -3891   3.15E-11  2
  1986ATK69   1,3-Butadiene + ·OH → Products  299 - 424   1.39E-11       -3891      2
  1986ATK69   CH2=CHCHO + ·OH → Products  298   1.96E-11           1.96E-11  2
  1986ATK69   (CH3)2CH(CH2)2CH3 + ·OH → Other Products + H2O  298   5.50E-12           5.50E-12  2
  1986ATK69   iso-C4H9COCH3 + ·OH → Products  297   1.41E-11              2
  1986ATK69   1,3-Dimethylbenzene + ·OH → Products  250 - 325   1.66E-11       -964   2.45E-11  2
  1986ATK69   1,3-Dimethylbenzene + ·OH → Products  450 - 1000   1.52E-12   2.00   1056      2
  1986ATK69   3-Methylphenol + ·OH → Products  300   5.71E-11              2
  1986ATK69   (iso-C4H9)2CO + ·OH → Products  299   2.71E-11              2
  1986ATK69   Toluene + ·OH → Products  220 - 325   2.09E-12       -2677   6.16E-12  2
  1986ATK69   Toluene + ·OH → Products  450 - 1000   6.74E-13   2.00   -91.46      2
  1986ATK69   n-C5H12 + ·OH → Other Products + H2O  299   4.05E-12              2
  1986ATK69   Tetrahydrofuran + ·OH → Products  300   1.50E-11              2
  1986ATK69   Furan + ·OH → Products  250 - 420   1.32E-11       -2777   4.04E-11  2
  1986ATK69   Thiophene + ·OH → Products  250 - 420   3.20E-12       -2694   9.51E-12  2
  1986ATK69   1-C6H14 + ·OH → Other Products + H2O  298   5.58E-12           5.58E-12  2
  1986ATK69   Cyclohexane + ·OHCyclohexyl + H2O  290 - 500   2.71E-11       3243   7.31E-12  2
  1986ATK69   Cyclohexene + ·OH → Products  298   6.74E-11           6.74E-11  2
  1986ATK69   n-C8H18 + ·OH → Other Products + H2O  290 - 500   3.12E-11       3159   8.72E-12  2
  1986ATK69   n-C9H20 + ·OH → Other Products + H2O  298   1.00E-11           1.00E-11  2
  1986ATK69   CH3CH=CH2 + ·OH → Products  290 - 467   4.85E-12       -4190   2.63E-11  2
  1986ATK69   CH3CH=CH2 + ·OH → Products  701 - 896   3.30E-11       1.28E04      2
  1986ATK69   CH3CH=CH2 + ·OH → Products  960 - 1210   8.40E-11       2.39E04      2
  1986ATK69   (CH3)2O + ·OHH2O + CH3OCH2  295 - 442   1.04E-11       3093   2.99E-12  2
  1986ATK69   iso-C4H8 + ·OH → Products  297 - 424   9.51E-12       -4182   5.15E-11  2
  1986ATK69   C2H5CHO + ·OH → Products  298   1.96E-11           1.96E-11  2
  1986ATK69   1-C10H22 + ·OH → Other Products + H2O  298   1.12E-11           1.12E-11  2
  1986ATK69   C2Cl4 + ·OH → Products  250 - 420   9.65E-12       1.01E04   1.66E-13  2
  1986ATK69   beta-pinene + ·OH → Products  297 - 423   2.36E-11       -2968   7.81E-11  2
  1986ATK69   1-C7H16 + ·OH → Other Products + H2O  298   7.21E-12           7.21E-12  2
  1986ATK69   Cyclopentane + ·OHCyclopentyl + H2O  298   5.20E-12           5.20E-12  2
  1986ATK69   CF3CHCl2 + ·OHH2O + CF3CCl2  280 - 420   1.16E-12       8813   3.31E-14  2
  1986ATK69   CH2=C=CH2 + ·OH → Products  299 - 421   5.86E-12       -1272      2
  1986ATK69   neo-C5H12 + ·OHNeopentyl + H2O  250 - 900   1.55E-12   2.00   1488   8.50E-13  2
  1986ATK69   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  290 - 500   1.12E-11       2494   4.10E-12  2
  1986ATK69   (CH3)2C=CHCH3 + ·OH → Products  298 - 425   1.93E-11       -3742   8.72E-11  2
  1986ATK69   (CH3)2CHCH2C(CH3)3 + ·OH → Other Products + H2O  290 - 500   1.62E-11       3683   3.66E-12  2
  1986ATK69   (CH3)2CHCH=CH2 + ·OH → Products  299 - 423   5.33E-12       -4432      2
  1986ATK69   (CH3)2C=C(CH3)2 + ·OH → Products  298   1.10E-10           1.10E-10  2
  1986ATK69   (Z)-2-C4H8 + ·OH → Products  298 - 425   1.09E-11       -4057   5.60E-11  2
  1986ATK69   CH3F + ·OH·CH2F + H2O  290 - 480   4.88E-13   2.00   8314   1.70E-14  2
  1986ATK69   CH2FCl + ·OHH2O + ·CClFH  250 - 500   3.35E-13   2.00   5022   4.42E-14  2
  1986ATK69   (CH3)3CC(CH3)3 + ·OHH2O + (CH3)3CC(CH3)2CH2  290 - 750   1.66E-12   2.00   1106   1.06E-12  2
  1986ATK69   (E)-2-C4H8 + ·OH → Products  298 - 425   1.01E-11       -4565   6.37E-11  2
  1986ATK69   CF3CH2F + ·OHH2O + CF3CHF  280 - 420   1.13E-13   2.00   6394   8.56E-15  2
  1986ATK69   Benzene-d6 + ·OH → Products  250 - 325   1.54E-12       748   1.14E-12  2
  1986ATK69   Benzene-d6 + ·OH → Products  450 - 1000   1.98E-13   2.00   4839      2
  1986ATK69   C6D5CD3 + ·OH → Products  250 - 325   7.32E-12       366   6.32E-12  2
  1986ATK69   C6D5CD3 + ·OH → Products  450 - 1000   6.08E-13   2.00   2295      2
  1986ATK69   S=C(CH3)SCH3 + ·OH → Products  249 - 367   5.11E-11       -3442   2.05E-10  2
  1986ATK69   CF3CHFCl + ·OH → CF3CFCl· + H2O  280 - 420   6.39E-13       1.02E04   1.03E-14  2
  1986ATK69   CF3CHFCl + ·OH → CF3CFCl· + H2O  280 - 420   8.10E-14   2.00   5188   9.98E-15  2
  1986ATK69   ·OH + (E)-CH3CH=CHCHO → Products  298   3.60E-11           3.60E-11  2

Search returned 110 records.