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Accessibility information
Author(s):   Barnes, I.; Bastian, V.; Becker, K.H.; Fink, E.H.; Nelsen, W.
Title:   Oxidation of sulphur compounds in the atmosphere: I. Rate constants of OH radical reactions with sulphur dioxide, hydrogen sulphide, aliphatic thiols and thiophenol
Journal:   J. Atmos. Chem.
Volume:   4
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986BAR/BAS445

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1986BAR/BAS445   CH3SH + ·OH → Products  300   3.60E-11              2
  1986BAR/BAS445   CH3SH + ·OH → Products  300   1.43              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   C2H5SH + ·OH → Products  300   4.50E-11              2
  1986BAR/BAS445   C2H5SH + ·OH → Products  300   1.79              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   iso-C3H7SH + ·OH → Products  300   3.90E-11              2
  1986BAR/BAS445   iso-C3H7SH + ·OH → Products  300   1.57              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   tert-C4H9SH + ·OH → Products  300   2.91E-11              2
  1986BAR/BAS445   tert-C4H9SH + ·OH → Products  300   1.18              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   1-C4H10 + ·OH → Other Products + H2O  300   2.41E-12              2
  1986BAR/BAS445   1-C4H10 + ·OH → Other Products + H2O  300   0.32              2
  Reference reaction:  C2H4 + ·OH → Products 2
  1986BAR/BAS445   n-C3H7SH + ·OH → Products  300   5.30E-11              2
  1986BAR/BAS445   n-C3H7SH + ·OH → Products  300   2.13              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   Benzenethiol + ·OH → Products  300   1.10E-11              2
  1986BAR/BAS445   Benzenethiol + ·OH → Products  300   1.98              2
  Reference reaction:  1-C6H14 + ·OH → Products 2
  1986BAR/BAS445   n-C4H9SH + ·OH → Products  300   5.60E-11              2
  1986BAR/BAS445   n-C4H9SH + ·OH → Products  300   2.24              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   1-C6H14 + ·OH → Other Products + H2O  300   5.60E-12              2
  1986BAR/BAS445   1-C6H14 + ·OH → Other Products + H2O  300   0.70              2
  Reference reaction:  C2H4 + ·OH → Products 2
  1986BAR/BAS445   CH3CH=CH2 + ·OH → Products  300   2.61E-11              2
  1986BAR/BAS445   CH3CH=CH2 + ·OH → Products  300   3.30              2
  Reference reaction:  C2H4 + ·OH → Products 2
  1986BAR/BAS445   iso-C4H9SH + ·OH → Products  300   4.60E-11              2
  1986BAR/BAS445   iso-C4H9SH + ·OH → Products  300   1.84              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   sec-C4H9SH + ·OH → Products  300   3.80E-11              2
  1986BAR/BAS445   sec-C4H9SH + ·OH → Products  300   1.52              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   CH3CH2CH(CH3)CH2SH + ·OH → Products  300   5.20E-11              2
  1986BAR/BAS445   CH3CH2CH(CH3)CH2SH + ·OH → Products  300   2.09              2
  Reference reaction:  CH3CH=CH2 + ·OH → Products 2
  1986BAR/BAS445   ·OH + SO2 → Products  300   1.10E-12              2
  1986BAR/BAS445   ·OH + SO2 → Products  300   0.42              2
  Reference reaction:  1-C4H10 + ·OH → Products 2
  1986BAR/BAS445   ·OH + H2SH2O + SH  300   5.20E-12              2
  1986BAR/BAS445   ·OH + H2SH2O + SH  300   0.65              2
  Reference reaction:  C2H4 + ·OH → Products 2

Search returned 30 records.