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Accessibility information
Author(s):   Baulch, D.L.; Bowers, D.G.; Malcolm, D.G.; Tuckersman, R.T.
Title:   Evaluated kinetic data for high-temperature reactions. Volume 5. Part 1. Homogeneous gas phase reactions of the hydroxyl radical with alkanes
Journal:   J. Phys. Chem. Ref. Data
Volume:   15
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986BAU/BOW465

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1986BAU/BOW465   CH4 + ·OH·CH3 + H2O  230 - 2000   4.63E-13   2.13   1.02E04   7.47E-15  2
  1986BAU/BOW465   C2H6 + ·OH·C2H5 + H2O  250 - 1200   2.32E-11       1.11E04   2.59E-13  2
  1986BAU/BOW465   C3H8 + ·OH → Other Products + H2O  290 - 1200   3.24E-13   2.93   -3243   1.20E-12  2
  1986BAU/BOW465   iso-C4H10 + ·OH → Other Products + H2O  290 - 750   1.48E-13   3.10   -7150   2.65E-12  2
  1986BAU/BOW465   (CH3)3CCH2CH3 + ·OH → Other Products + H2O  298   2.66E-12           2.66E-12  2
  1986BAU/BOW465   iso-C5H12 + ·OH → Other Products + H2O  298   3.99E-12           3.99E-12  2
  1986BAU/BOW465   (CH3)2CHCH(CH3)2 + ·OH → Other Products + H2O  298   5.81E-12           5.81E-12  2
  1986BAU/BOW465   (C2H5)2CHCH3 + ·OH → Other Products + H2O  298   6.14E-12           6.14E-12  2
  1986BAU/BOW465   1-C4H10 + ·OH → Other Products + H2O  300 - 750   2.74E-12   1.30          2
  1986BAU/BOW465   (CH3)2CH(CH2)2CH3 + ·OH → Other Products + H2O  298   5.65E-12           5.65E-12  2
  1986BAU/BOW465   Pentane, 2,4-dimethyl- + ·OH → Other Products + H2O  298   5.48E-12           5.48E-12  2
  1986BAU/BOW465   Methylcyclohexane + ·OH → Products  298   1.10E-11           1.10E-11  2
  1986BAU/BOW465   n-C5H12 + ·OH → Other Products + H2O  298   4.15E-12           4.15E-12  2
  1986BAU/BOW465   1-C6H14 + ·OH → Other Products + H2O  298   5.81E-12           5.81E-12  2
  1986BAU/BOW465   Cyclohexane + ·OHCyclohexyl + H2O  298   7.47E-12           7.47E-12  2
  1986BAU/BOW465   n-C8H18 + ·OH → Other Products + H2O  298   9.13E-12           9.13E-12  2
  1986BAU/BOW465   n-C9H20 + ·OH → Other Products + H2O  298   1.10E-11           1.10E-11  2
  1986BAU/BOW465   1-C10H22 + ·OH → Other Products + H2O  298   1.18E-11           1.18E-11  2
  1986BAU/BOW465   1-C7H16 + ·OH → Other Products + H2O  298   7.47E-12           7.47E-12  2
  1986BAU/BOW465   Cyclobutane + ·OHCyclobutyl + H2O  298   1.16E-12           1.16E-12  2
  1986BAU/BOW465   Cyclopentane + ·OHCyclopentyl + H2O  298   4.98E-12           4.98E-12  2
  1986BAU/BOW465   neo-C5H12 + ·OHNeopentyl + H2O  300 - 1000   1.11E-12   2.08   582      2
  1986BAU/BOW465   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  298   4.32E-12           4.32E-12  2
  1986BAU/BOW465   (CH3)2CHCH2C(CH3)3 + ·OH → Other Products + H2O  298   3.82E-12           3.82E-12  2
  1986BAU/BOW465   (CH3)3CC(CH3)3 + ·OHH2O + (CH3)3CC(CH3)2CH2  300 - 700   1.50E-12   2.00   748      2

Search returned 25 records.