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Accessibility information
Author(s):   Borchardt, D.B.; Bauer, S.H.
Title:   Intramolecular conversions over low barriers. VII. The aziridine inversion-intrinsically non-RRKM
Journal:   J. Chem. Phys.
Volume:   85
Year:   1986
Reference type:   Journal article
Squib:   1986BOR/BAU4980

Reaction:   Aziridine → Products
Reaction order:   1
Temperature:   299 - 388 K
Pressure:  6.67E-3 - 1.47 bar
Rate expression:   2.1x1017 [s-1] e-66100 [J/mole]/RT
Bath gas:   SF6
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Nuclear magnetic resonance (NMR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
299 5.96E5
300 6.51E5
325 5.00E6
350 2.87E7
375 1.30E8
388 2.65E8