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Author(s):   Buxton, J.P.; Simpson, C.J.S.M.
Title:   Thermal decarbonylations of unsaturated cyclic ketones: Kinetics and dynamics
Journal:   Chem. Phys.
Volume:   105
Year:   1986
Reference type:   Journal article
Squib:   1986BUX/SIM307

Reaction:   3-Cyclopenten-1-one1,3-Butadiene + CO
Reaction order:   1
Temperature:   1150 - 1190 K
Pressure:  7.60E-3 - 0.81 bar
Rate expression:   6.31x1013 [s-1] e-193727 [±9728 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Other (IR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1150 1.00E5
1175 1.54E5
1190 1.98E5