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Author(s):   Dominguez, R.M.; Rotinov, A.; Chuchani, G.
Title:   Correlation of alkyl and polar groups in the gas-phase pyrolysis kinetics of α-substituted ethyl chlorides
Journal:   J. Phys. Chem.
Volume:   90
Page(s):   6277 - 6281
Year:   1986
Reference type:   Journal article
Squib:   1986DOM/ROT6277-6281

Reaction:   CH3CHClCNCH2CHCN + HCl
Reaction order:   1
Temperature:   370 - 490 K
Pressure:  3.73E-2 - 0.40 bar
Rate expression:   2.82x1013 [s-1] e-236131 [±7084 J/mole]/RT
Uncertainty:   5.0
Bath gas:   CH3CH=CH2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
370 1.30E-20
375 3.63E-20
400 4.12E-18
425 2.69E-16
450 1.10E-14
475 3.05E-13
490 1.90E-12