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Author(s):   Finlayson-Pitts, B.J.; Ezell, M.J.; Grant, C.E.
Title:   Temperature dependence of the OH + ClNO reaction: Evidence for two competing reaction channels
Journal:   J. Phys. Chem.
Volume:   90
Year:   1986
Reference type:   Journal article
Squib:   1986FIN/EZE17

Reaction:   NOCl + ·OHHOCl + NO
Reaction order:   2
Temperature:   298 - 373 K
Pressure:  1.33E-3 bar
Rate expression:   2.01x10-12 [cm3/molecule s] e-3875 [±2245 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 4.21E-13
300 4.25E-13
325 4.79E-13
350 5.31E-13
373 5.76E-13