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Accessibility information
Author(s):   Gajewski, J.J.; Hawkins, C.M.
Title:   Gas-phase pyrolysis of isotopically and stereochemically labeled α-pinene: Evidence for a nonrandomized intermediate
Journal:   J. Am. Chem. Soc.
Volume:   108
Year:   1986
Reference type:   Journal article
Squib:   1986GAJ/HAW838

Reaction:   (1S)-2,6,6-Trimethylbicyclo[3.1.1]hept-2-ened-Limonene
Reaction order:   1
Temperature:   474 - 513 K
Rate expression:   5.01x1013 [s-1] e-175435 [J/mole]/RT
Uncertainty:   1.25999999
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
474 2.33E-6
475 2.56E-6
500 2.36E-5
513 6.87E-5