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Accessibility information
Author(s):   Grela, M.A.; Colussi, A.J.
Title:   Kinetics and mechanism of the thermal decomposition of unsaturated aldehydes: Benzaldehyde, 2-butenal, and 2-furaldehyde
Journal:   J. Phys. Chem.
Volume:   90
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986GRE/COL434

Reaction:   Benzaldehyde → benzoyl +
Reaction order:   1
Temperature:   1170 - 1240 K
Rate expression:   3.98x1015 [s-1] e-350039 [J/mole]/RT
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1170 9.39E-1
1175 1.09E0
1200 2.31E0
1225 4.72E0
1240 7.16E0