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Accessibility information
Author(s):   Grela, M.A.; Colussi, A.J.
Title:   Kinetics and mechanism of the thermal decomposition of unsaturated aldehydes: Benzaldehyde, 2-butenal, and 2-furaldehyde
Journal:   J. Phys. Chem.
Volume:   90
Year:   1986
Reference type:   Journal article
Squib:   1986GRE/COL434

Reaction:   (E)-CH3CH=CHCHOCH3CH=CH2 + CO
Reaction order:   1
Temperature:   1040 - 1170 K
Rate expression:   3.16x1013 [s-1] e-249434 [J/mole]/RT
Uncertainty:   2.0
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1040 9.37E0
1050 1.23E1
1075 2.40E1
1100 4.52E1
1125 8.29E1
1150 1.48E2
1170 2.31E2