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Accessibility information
Author(s):   Husain, D.; Marshall, P.
Title:   Determination of absolute rate data for the reactions of atomic sodium, Na(32S1/2), with CH3F, CH3Cl, CH3Br, HCl, and HBr as a function of temperature by time-resolved atomic resonance spectroscopy
Journal:   Int. J. Chem. Kinet.
Volume:   18
Year:   1986
Reference type:   Journal article
Squib:   1986HUS/MAR83

Reaction:   CH3Cl + Na·CH3 + NaCl
Reaction order:   2
Temperature:   770 - 892 K
Pressure:  5.20E-2 bar
Rate expression:   8.0x10-10 [±4.98x10-10 cm3/molecule s] e-43984 [±3958 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
770 8.31E-13
775 8.69E-13
800 1.08E-12
825 1.31E-12
850 1.59E-12
875 1.90E-12
892 2.13E-12