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Accessibility information
Author(s):   Koda, S.; Tanaka, M.
Title:   Ignition of premixed methanol/air in a heated flow tube and the effect of NO2 addition
Journal:   Combust. Sci. Technol.
Volume:   47
Page(s):   165 - 176
Year:   1986
Reference type:   Journal article
Squib:   1986KOD/TAN165-176

Reaction:   CH3OH + NO2(·)CH2OH + HNO2
Reaction order:   2
Temperature:   900 - 1100 K
Pressure:  1.01 bar
Rate expression:   3.32x10-13 [cm3/molecule s] e-94785 [J/mole]/RT
Uncertainty:   2.0
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
900 1.05E-18
925 1.48E-18
950 2.04E-18
975 2.78E-18
1000 3.72E-18
1025 4.91E-18
1050 6.40E-18
1075 8.24E-18
1100 1.05E-17