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Accessibility information
Author(s):   Lifshitz, A.; Bidani, M.; Bidani, S.
Title:   Thermal reactions of cyclic ethers at high temperatures. 2. Pyrolysis of tetrahydrofuran behind reflected shocks
Journal:   J. Phys. Chem.
Volume:   90
Page(s):  
Year:   1986
Reference type:   Journal article
Squib:   1986LIF/BID3422

Reaction:   TetrahydrofuranCH2O + CH3CH=CH2
Reaction order:   1
Temperature:   1070 - 1530 K
Pressure:  2.13 - 8.61 bar
Rate expression:   8.24x1015 [s-1] e-347545 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1070 8.91E-2
1075 1.07E-1
1100 2.59E-1
1125 6.02E-1
1150 1.35E0
1175 2.93E0
1200 6.14E0
1225 1.25E1
1250 2.47E1
1275 4.76E1
1300 8.95E1
1325 1.64E2
1350 2.94E2
1375 5.17E2
1400 8.89E2
1425 1.50E3
1450 2.49E3
1475 4.06E3
1500 6.51E3
1525 1.03E4
1530 1.12E4