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Author(s):   Muller-Markgraf, W.; Troe, J.
Title:   Shock wave study of benzyl UV absorption spectra: revised toluene and benzyl decomposition rates
Journal:   Symp. Int. Combust. Proc.
Volume:   21
Page(s):   815 - 824
Year:   1986
Reference type:   Journal article
Squib:   1986MUL/TRO815-824

Reaction:   TolueneBenzyl +
Reaction order:   1
Temperature:   1500 - 1900 K
Pressure:  0.74 - 1.00 bar
Rate expression:   2.0x1015 [s-1] e-369163 [±7383 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1500 2.79E2
1525 4.54E2
1550 7.25E2
1575 1.14E3
1600 1.78E3
1625 2.72E3
1650 4.12E3
1675 6.15E3
1700 9.08E3
1725 1.33E4
1750 1.92E4
1775 2.74E4
1800 3.88E4
1825 5.43E4
1850 7.55E4
1875 1.04E5
1900 1.42E5