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Accessibility information
Author(s):   Robaugh, D.A.; Stein, S.E.
Title:   Stabilities of highly conjugated radicals from bond homolysis rates
Journal:   J. Am. Chem. Soc.
Volume:   108
Page(s):   3224 - 3229
Year:   1986
Reference type:   Journal article
Squib:   1986ROB/STE3224-3229

Reaction:   1,1'-Diphenylethane·CH3 + Diphenylmethyl
Reaction order:   1
Temperature:   1000 - 1070 K
Rate expression:   3.16x1015 [s-1] e-282692 [J/mole]/RT
Bath gas:   2,2'-Diphenylpropane
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 5.42E0
1025 1.24E1
1050 2.73E1
1070 5.01E1