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Accessibility information
Author(s):   Robaugh, D.A.; Stein, S.E.
Title:   Stabilities of highly conjugated radicals from bond homolysis rates
Journal:   J. Am. Chem. Soc.
Volume:   108
Page(s):   3224 - 3229
Year:   1986
Reference type:   Journal article
Squib:   1986ROB/STE3224-3229

Reaction:   4-Ethylstyrene·CH3 + 4-Vinylbenzyl
Reaction order:   1
Temperature:   1100 - 1190 K
Rate expression:   2.0x1015 [s-1] e-298490 [J/mole]/RT
Bath gas:   4-Ethylstyrene
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 1.34E1
1125 2.77E1
1150 5.54E1
1175 1.08E2
1190 1.58E2