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Accessibility information
Author(s):   Robaugh, D.; Tsang, W.
Title:   Mechanism and rate of hydrogen atom attack on toluene at high temperature
Journal:   J. Phys. Chem.
Volume:   90
Page(s):   4159 - 4163
Year:   1986
Reference type:   Journal article
Squib:   1986ROB/TSA4159-4163

Reaction:   Toluene + H2 + Benzyl
Reaction order:   2
Reference reaction:   Toluene + Benzene + ·CH3
Reference reaction order:   2
Temperature:   950 - 1100 K
Pressure:  2.03 - 5.07 bar
Rate expression:   9.79 e-12971 [J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
950 1.90E0
975 1.98E0
1000 2.06E0
1025 2.14E0
1050 2.22E0
1075 2.29E0
1100 2.37E0