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Author(s):   Sutherland, J.W.; Michael, J.V.; Klemm, R.B.
Title:   Rate constant for the O(3P) + CH4 →’ OH + CH3 reaction obtained by the flash photolysis-shock tube technique over the temperature range 763 ≤ T ≤ 1755 K
Journal:   J. Phys. Chem.
Volume:   90
Year:   1986
Reference type:   Journal article
Squib:   1986SUT/MIC5941

Reaction:   CH4 + ·CH3 + ·OH
Reaction order:   2
Temperature:   400 - 2250 K
Rate expression:   8.32x10-12 [cm3/molecule s] (T/298 K)1.56 e-35503 [J/mole]/RT
Bath gas:   He
Category:  Review
Data type:   Experimental value and limited review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
400 3.04E-16
500 3.65E-15
600 2.01E-14
700 7.07E-14
800 1.87E-13
900 4.06E-13
1000 7.69E-13
1100 1.32E-12
1200 2.08E-12
1300 3.10E-12
1400 4.40E-12
1500 6.01E-12
1600 7.94E-12
1700 1.02E-11
1800 1.28E-11
1900 1.58E-11
2000 1.92E-11
2100 2.29E-11
2200 2.70E-11
2250 2.92E-11