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Author(s):   Timonen, R.; Kalliorinne, K.; Koskikallio, J.
Title:   Kinetics of reactions of methyl and ethyl radicals with chlorine in the gas phase studied by photochlorination of methane
Journal:   Acta Chem. Scand. Ser. A
Volume:   40
Page(s):   459 - 466
Year:   1986
Reference type:   Journal article
Squib:   1986TIM/KAL459-466

Reaction:   ·CH3 + ·ClCH3Cl
Reaction order:   2
Temperature:   298 - 423 K
Pressure:  3.00E-2 - 7.00E-2 bar
Rate expression:   2.56x10-10 [±6.64x10-11 cm3/molecule s]
Bath gas:   Xe
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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