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Author(s):   Tsang, W.; Robaugh, D.; Mallard, W.G.
Title:   Single-pulse shock-tube studies on C-NO2 bond cleavage during the decomposition of some nitro aromatic compounds
Journal:   J. Phys. Chem.
Volume:   90
Year:   1986
Reference type:   Journal article
Squib:   1986TSA/ROB5968

Reaction:   Benzene, 1-methyl-4-nitro- → Phenyl, 4-methyl- + NO2
Reaction order:   1
Reference reaction:   Cyclohexene, 1,2-dimethyl-C2H4 + CH2=C(CH3)C(CH3)=CH2
Temperature:   1070 - 1180 K
Pressure:  3.44 - 4.45 bar
Rate expression:   7.69x1014 [s-1] e-268557 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1070 5.97E1
1075 6.87E1
1100 1.36E2
1125 2.61E2
1150 4.87E2
1175 8.86E2
1180 9.95E2