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Author(s):   Tschuikow-Roux, E.; Faraji, F.; Niedzielski, J.
Title:   Rate constants and kinetic isotope effects for hydrogen/deuterium abstraction by chlorine atoms from the chloromethyl group in CH₂ClCH₂Cl, CD₂ClCD₂Cl, CH₂ClCHCl₂, and CH₂ClCDCl₂
Journal:   Int. J. Chem. Kinet.
Volume:   18
Page(s):   513 - 527
Year:   1986
Reference type:   Journal article
Squib:   1986TSC/FAR513-527

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1986TSC/FAR513-527	CHCl₂CH₂Cl + ·Cl → HCl + CHCl₂CHCl	273 - 368	1.68E-11	1.63E04	2.33E-14	2
1986TSC/FAR513-527	CHCl₂CH₂Cl + ·Cl → HCl + CH₂ClCCl₂·	273 - 368	2.03E-11	1.41E04	6.75E-14	2
1986TSC/FAR513-527	CH₂ClCH₂Cl + ·Cl → HCl + CH₂ClCHCl·	273 - 368	4.93E-11	9063	1.27E-12	2
1986TSC/FAR513-527	·Cl + CD₂ClCD₂Cl → Products	273 - 368	2.92E-11	1.13E04	3.05E-13	2

Search returned 4 records.