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Author(s):   Tschuikow-Roux, E.; Faraji, F.; Niedzielski, J.
Title:   Rate constants and kinetic isotope effects for hydrogen/deuterium abstraction by chlorine atoms from the chloromethyl group in CH2ClCH2Cl, CD2ClCD2Cl, CH2ClCHCl2, and CH2ClCDCl2
Journal:   Int. J. Chem. Kinet.
Volume:   18
Page(s):   513 - 527
Year:   1986
Reference type:   Journal article
Squib:   1986TSC/FAR513-527

Reaction:   CH2ClCH2Cl + ClHCl + CH2ClCHCl·
Reaction order:   2
Reference reaction:   CH4 + Cl·CH3 + HCl
Temperature:   273 - 368 K
Pressure:  2.80E-2 bar
Rate expression:   4.93x10-11 [±9.3x10-12 cm3/molecule s] e-9063 [±542 J/mole]/RT
Bath gas:   CH2ClCH2Cl
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 9.10E-13
275 9.37E-13
300 1.30E-12
325 1.72E-12
350 2.19E-12
368 2.55E-12