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Author(s):   van Mele, B.; Boon, G.; Huybrechts, G.
Title:   Gas phase kinetic and thermochemical data for endo- and exo-5-monosubstituted bicyclo[2.2.2]oct-2-enes
Journal:   Int. J. Chem. Kinet.
Volume:   18
Year:   1986
Reference type:   Journal article
Squib:   1986VAN/BOO537

Reaction:   bicyclo[2.2.2]oct-2-ene, 5-ethyl-,(1α,4α,5β)-1-C4H8 + 1,3-Cyclohexadiene
Reaction order:   1
Temperature:   567 - 670 K
Pressure:  4.00E-3 - 1.07E-2 bar
Rate expression:   1.66x1015 [s-1] e-244445 [J/mole]/RT
Uncertainty:   1.10000002
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
567 5.02E-8
575 1.03E-7
600 8.70E-7
625 6.18E-6
650 3.77E-5
670 1.46E-4