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Accessibility information
Author(s):   Yano, T.; Tschuikow-Roux, E.
Title:   Competitive photochlorination of the fluoroethanes CH3CHF2, CH2FCH2F and CHF2CHF2
Journal:   J. Photochem.
Volume:   32
Year:   1986
Reference type:   Journal article
Squib:   1986YAN/TSC25

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1986YAN/TSC25   CH3CHF2 + ·ClHCl + CH3CF2  280 - 360   7.52E-12       8298   2.64E-13  2
  1986YAN/TSC25   CH3CHF2 + ·ClHCl + CH2CHF2  280 - 360   8.40E-12       2.02E04   2.42E-15  2
  1986YAN/TSC25   CHF2CHF2 + ·ClHCl + CHF2CF2  280 - 360   9.65E-12       2.06E04   2.35E-15  2
  1986YAN/TSC25   CH2FCH2F + ·ClHCl + CH2FCHF  280 - 360   2.99E-11       9146   7.45E-13  2

Search returned 4 records.