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Accessibility information
Author(s):   Zaslonko, I.S.; Mukoseev, Yu.I.; Skorobogatove, G.A.; Slinkin, S.V.
Title:   Parameters of the thermal dissociation of gaseous CF3I
Journal:   Kinet. Catal.
Volume:   27
Year:   1986
Reference type:   Journal article
Squib:   1986ZAS/MUK636

Reaction:   CF3I·CF3 + I
Reaction order:   1
Temperature:   600 - 1450 K
Pressure:  0.60 - 11.31 bar
Rate expression:   2.51x1014 [s-1] e-220334 [±4407 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
600 1.65E-5
650 4.94E-4
700 9.09E-3
750 1.13E-1
800 1.03E0
850 7.24E0
900 4.09E1
950 1.93E2
1000 7.78E2
1050 2.75E3
1100 8.65E3
1150 2.47E4
1200 6.44E4
1250 1.56E5
1300 3.52E5
1350 7.49E5
1400 1.51E6
1450 2.90E6