Kinetics Database Resources
Title: The mechanism of thermal eliminations. Part 22. Rate data for pyrolysis of primary, secondary, and tertiary β-hydroxy esters, and β-hydroxy ketones. The dependence of transition-state structure for six-centre eliminations upon compound type
Journal: J. Chem. Soc. Perkin Trans. 2
Reference type: Journal article
Rate expression: k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order: s-1
Second order: cm3/molecule s
Third order: cm6/molecule2 s
R = 8.314472 J / mole K
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