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Author(s):   Chasovnikov, S.A.; Krasnoperov, L.N.
Title:   Determination of the rate constant of the reaction of the silyl radical with oxygen and nitrosyl chloride by laser-photolysis-laser-magnetic resonance with time resolution
Journal:   Khim. Fiz.
Volume:   6
Page(s):   956 - 959
Year:   1987
Reference type:   Journal article
Squib:   1987CHA/KRA956-959

Reaction:   NOCl + SiH3 → Products
Reaction order:   2
Temperature:   298 K
Pressure:  0.93 bar
Rate expression:   1.3x10-11 [±2.99x10-12 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser magnetic resonance (LMR)

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