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Accessibility information
Author(s):   Cohen, N.; Benson, S.W.
Title:   Empirical correlations for rate coefficients for reactions of OH with haloalkanes
Journal:   J. Phys. Chem.
Volume:   91
Page(s):   171 - 175
Year:   1987
Reference type:   Journal article
Squib:   1987COH/BEN171-175

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987COH/BEN171-175   CHCl3 + ·OH·CCl3 + H2O  290 - 306   1.22E-12       4656   1.86E-13  2
  1987COH/BEN171-175   CH3CCl3 + ·OHH2O + CCl3CH2  290 - 306   3.35E-12       1.54E04   6.75E-15  2
  1987COH/BEN171-175   C2H6 + ·OH·C2H5 + H2O  290 - 306   2.32E-11       9562   4.90E-13  2
  1987COH/BEN171-175   CH3Cl + ·OH·CH2Cl + H2O  290 - 360   8.65E-12       1.32E04   4.17E-14  2
  1987COH/BEN171-175   C2H5Cl + ·OH → Other Products + H2O  290 - 306   4.45E-12       5238   5.37E-13  2
  1987COH/BEN171-175   CH2Cl2 + ·OHCHCl2 + H2O  290 - 306   3.39E-12       8896   9.34E-14  2
  1987COH/BEN171-175   CH2F2 + ·OH·CHF2 + H2O  290 - 306   5.53E-12       1.60E04   8.51E-15  2
  1987COH/BEN171-175   CH3CHCl2 + ·OH → Other Products + H2O  290 - 306   1.46E-12       998   9.78E-13  2
  1987COH/BEN171-175   CH3CHF2 + ·OH → Other Products + H2O  290 - 306   2.18E-12       8148   8.12E-14  2
  1987COH/BEN171-175   CHFCl2 + ·OH·CCl2F + H2O  290 - 306   1.42E-12       8231   5.13E-14  2
  1987COH/BEN171-175   CHF2Cl + ·OH·CClF2 + H2O  290 - 306   1.66E-12       1.18E04   1.42E-14  2
  1987COH/BEN171-175   CH3CF2Cl + ·OH → CF2ClCH2· + H2O  298 - 306   4.43E-12       1.54E04   8.93E-15  2
  1987COH/BEN171-175   CF3CH2Cl + ·OHH2O + CF3CHCl  290 - 306   2.37E-12       1.11E04   2.65E-14  2
  1987COH/BEN171-175   CHCl2CH2Cl + ·OH → Other Products + H2O  290 - 306   1.11E-11       7732   4.89E-13  2
  1987COH/BEN171-175   CF3CHCl2 + ·OHH2O + CF3CCl2  290 - 306   9.45E-13       6818   6.03E-14  2
  1987COH/BEN171-175   C2H5F + ·OH → Other Products + H2O  290 - 306   5.83E-12       8813   1.66E-13  2
  1987COH/BEN171-175   C2F5H + ·OHC2F5 + H2O  290 - 306   1.20E-12       1.40E04   4.28E-15  2
  1987COH/BEN171-175   CHF2CHF2 + ·OHH2O + CHF2CF2  290 - 306   2.74E-12       1.06E04   3.74E-14  2
  1987COH/BEN171-175   CH2FCHF2 + ·OH → Other Products + H2O  290 - 306   5.28E-12       1.13E04   5.50E-14  2
  1987COH/BEN171-175   CH3F + ·OH·CH2F + H2O  290 - 306   1.26E-11       1.67E04   1.48E-14  2
  1987COH/BEN171-175   CH2FCl + ·OHH2O + ·CClFH  290 - 306   4.23E-12       1.25E04   2.76E-14  2
  1987COH/BEN171-175   CH2FCH2F + ·OHH2O + CH2FCHF  290 - 306   1.91E-12       7982   7.62E-14  2
  1987COH/BEN171-175   CF3CH2F + ·OHH2O + CF3CHF  290 - 306   2.79E-12       1.46E04   7.60E-15  2
  1987COH/BEN171-175   CF2ClCH2Cl + ·OH → ·CHClCClF2 + H2O  290 - 306   2.16E-12       1.11E04   2.41E-14  2
  1987COH/BEN171-175   CF3CHFCl + ·OH → CF3CFCl· + H2O  290 - 306   1.05E-12       1.04E04   1.58E-14  2

Search returned 25 records.