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Accessibility information
Author(s):   Dean, A.M.; Westmoreland, P.R.
Title:   Bimolecular QRRK analyss of methyl radical reactions
Journal:   Int. J. Chem. Kinet.
Volume:   19
Year:   1987
Reference type:   Journal article
Squib:   1987DEA/WES207

Reaction:   ·CH3 + ·OHCH3OH
Reaction order:   2
Temperature:   600 - 2500 K
Pressure:  1.01 bar
Rate expression:   1.91x10-4 [cm3/molecule s] (T/298 K)-8.20 e-48806 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
600 3.47E-11
700 3.96E-11
800 3.78E-11
900 3.25E-11
1000 2.63E-11
1100 2.05E-11
1200 1.57E-11
1300 1.19E-11
1400 8.92E-12
1500 6.70E-12
1600 5.04E-12
1700 3.80E-12
1800 2.88E-12
1900 2.20E-12
2000 1.68E-12
2100 1.30E-12
2200 1.01E-12
2300 7.85E-13
2400 6.16E-13
2500 4.86E-13