Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Pamidimukkala, K.M.; Kern, R.D.; Patel, M.R.; Wei, H.C.; Kiefer, J.H.
Title:   High-temperature pyrolysis of toluene
Journal:   J. Phys. Chem.
Volume:   91
Year:   1987
Reference type:   Journal article
Squib:   1987PAM/KER2148

Reaction:   Toluene·CH3 + Phenyl
Reaction order:   1
Temperature:   1600 - 2100 K
Pressure:  0.51 bar
Rate expression:   8.91x1012 [s-1] e-303478 [J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1600 1.10E3
1650 2.20E3
1700 4.22E3
1750 7.79E3
1800 1.39E4
1850 2.41E4
1900 4.04E4
1950 6.62E4
2000 1.06E5
2050 1.65E5
2100 2.52E5