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Accessibility information
Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part 2. Methanol
Journal:   J. Phys. Chem. Ref. Data
Volume:   16
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987TSA471

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987TSA471   CH2O + (·)CH2OHCH3OH + HCO  300 - 2500   7.72E-14   2.80   2.45E04      2
  1987TSA471   CH3OH·CH3 + ·OH  300 - 2500   1.90E16       3.84E05      1
  1987TSA471   CH3OH + ·C2HC2H2 + CH3  300 - 2500   2.01E-12              2
  1987TSA471   CH3OH + ·C2HC2H2 + (·)CH2OH  300 - 2500   1.00E-11              2
  1987TSA471   CH3OH + CH3O2·(·)CH2OH + CH3OOH  300 - 2500   3.01E-12       5.74E04      2
  1987TSA471   CH3OH + CH3CH3OH + (·)CH2OH  300 - 2500   5.00E-13       1.70E04      2
  1987TSA471   CH3OH + ·CH3CH4 + CH3  300 - 2500   1.12E-15   3.10   2.90E04      2
  1987TSA471   CH3OH + ·CH3CH4 + (·)CH2OH  300 - 2500   4.38E-15   3.20   3.00E04      2
  1987TSA471   CH3OH + (·)CH2OHCH3OH + CH3  300 - 2500   1.30E-14       5.05E04      2
  1987TSA471   CH3OH + HCOCH2O + (·)CH2OH  300 - 2500   2.41E-13   2.90   5.49E04      2
  1987TSA471   CH3OH + C2H3C2H4 + CH3  300 - 2500   1.12E-15   3.10   2.90E04      2
  1987TSA471   CH3OH + C2H3C2H4 + (·)CH2OH  300 - 2500   4.38E-15   3.20   3.00E04      2
  1987TSA471   CH3OH + CH3COCH3CHO + (·)CH2OH  300 - 2500   2.13E-13   3.00   5.16E04      2
  1987TSA471   CH3OH + HO2(·)CH2OH + H2O2  300 - 2500   1.60E-13       5.26E04      2
  1987TSA471   CH3OH + ·OH → Other Products + H2O  300 - 2500   1.69E-13   2.50   -4016      2
  1987TSA471   CH3OH + O2(·)CH2OH + HO2  300 - 2500   3.40E-11       1.88E05      2
  1987TSA471   CH3OH + → Products  300 - 2500   5.53E-12   2.10   2.04E04      2
  1987TSA471   CH3OH + ·C2H5C2H6 + CH3  300 - 2500   1.12E-15   3.10   3.74E04      2
  1987TSA471   CH3OH + ·C2H5C2H6 + (·)CH2OH  300 - 2500   4.38E-15   3.20   3.83E04      2
  1987TSA471   CH3OH + → Other Products + ·OH  300 - 2500   9.86E-13   2.50   1.29E04      2
  1987TSA471   CH3OH + ·CH2CH3 + ·CH3  300 - 2500   1.12E-15   3.10   2.90E04      2
  1987TSA471   CH3OH + ·CH2·CH3 + (·)CH2OH  300 - 2500   4.38E-15   3.20   3.00E04      2
  1987TSA471   CH4 + (·)CH2OHCH3OH + ·CH3  300 - 2500   1.68E-15   3.10   6.79E04      2
  1987TSA471   C2H6 + (·)CH2OHCH3OH + ·C2H5  300 - 2500   8.73E-15   3.00   5.85E04      2
  1987TSA471   C2H4 + (·)CH2OH → HOCH2CH2CH2·  300 - 2500   8.00E-14       2.91E04      2
  1987TSA471   C2H2 + (·)CH2OHCH2O + C2H3  300 - 2500   1.20E-12       3.77E04      2
  1987TSA471   H2 + (·)CH2OHCH3OH +   300 - 2500   9.96E-14   2.00   5.59E04      2
  1987TSA471   ·C2H + (·)CH2OHCH2O + C2H2  300 - 2500   5.99E-11              2
  1987TSA471   ·C2H + (·)CH2OHCH2C≡CH + ·OH  300 - 2500   2.01E-11              2
  1987TSA471   CH3O2· + (·)CH2OH → Products  300 - 2500   2.01E-11              2
  1987TSA471   CH3 + (·)CH2OHCH2O + CH3OH  300 - 2500   4.00E-11              2
  1987TSA471   ·CH3 + (·)CH2OHCH2O + CH4  300 - 2500   4.00E-12              2
  1987TSA471   ·CH3 + (·)CH2OHC2H5OH  300 - 2500   2.01E-11              2
  1987TSA471   (·)CH2OHCH2O +   300 - 2500   4.88E-05   -2.50   1.43E05      2
  1987TSA471   (·)CH2OHCH2O +   900 - 2500   0.31   -8.00   1.80E05      2
  1987TSA471   (·)CH2OH + (·)CH2OHCH2O + CH3OH  300 - 2500   8.00E-12              2
  1987TSA471   (·)CH2OH + (·)CH2OHHOCH2CH2OH  300 - 2500   1.60E-11              2
  1987TSA471   (·)CH2OH + HCOCH2O + CH2O  300 - 2500   3.01E-10              2
  1987TSA471   (·)CH2OH + HCOCH3OH + CO  300 - 2500   2.01E-10              2
  1987TSA471   (·)CH2OH + C2H3CH2O + C2H4  300 - 2500   5.00E-11              2
  1987TSA471   (·)CH2OH + C2H3·CH2CH=CH2 + ·OH  300 - 2500   2.01E-11              2
  1987TSA471   (·)CH2OH + CH3CO → Adduct  300 - 2500   2.01E-11              2
  1987TSA471   (·)CH2OH + HO2CH2O + H2O2  300 - 2500   2.01E-11              2
  1987TSA471   (·)CH2OH + ·OHCH2O + H2O  300 - 2500   4.00E-11              2
  1987TSA471   (·)CH2OH + H2O2CH3OH + HO2  300 - 2500   5.00E-15       1.08E04      2
  1987TSA471   (·)CH2OH + O2CH2O + HO2  300 - 2500   2.01E-12              2
  1987TSA471   (·)CH2OH + CH2O + H2  300 - 2500   1.00E-11              2
  1987TSA471   (·)CH2OH + ·CH3 + ·OH  300 - 2500   1.60E-10              2
  1987TSA471   ·C2H5 + (·)CH2OHCH2O + C2H6  300 - 2500   4.00E-12              2
  1987TSA471   ·C2H5 + (·)CH2OHCH3OH + C2H4  300 - 2500   4.00E-12              2
  1987TSA471   ·C2H5 + (·)CH2OHn-C3H7OH  300 - 2500   2.01E-11              2
  1987TSA471   (·)CH2OH + CH2O + ·OH  300 - 2500   7.01E-11              2
  1987TSA471   (·)CH2OH + ·CH2CH2O + ·CH3  300 - 2500   2.01E-12              2
  1987TSA471   (·)CH2OH + ·CH2C2H4 + ·OH  300 - 2500   4.00E-11              2

Search returned 54 records.