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Author(s):   Van Mele, B.; Huybrechts, G.
Title:   Kinetics and mechanism of the thermal reactions of endo- and exo-5-cyanobicyclo[2.2.2]oct-2-ene and methyl-substituted derivatives in the gas phase
Journal:   Int. J. Chem. Kinet.
Volume:   19
Year:   1987
Reference type:   Journal article
Squib:   1987VAN/HUY885

Reaction:   Bicyclo[2.2.2]oct-5-ene-2-carbonitrile,(1α,2α,4α)-CH2CHCN + 1,3-Cyclohexadiene
Reaction order:   1
Temperature:   518 - 605 K
Pressure:  1.07E-2 - 3.33E-2 bar
Rate expression:   6.76x1014 [s-1] e-226985 [J/mole]/RT
Uncertainty:   1.04999995
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
518 8.74E-9
525 1.76E-8
550 1.88E-7
575 1.62E-6
600 1.17E-5
605 1.71E-5