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Author(s):   Van Mele, B.; Tybaert, C.; Huybrechts, G.
Title:   Kinetics, mechanism, and stereochemistry of Diels-Alder reactions of carbonyl-substituted ethenes with cyclohexa-1,3-diene in the gas phase
Journal:   Int. J. Chem. Kinet.
Volume:   19
Year:   1987
Reference type:   Journal article
Squib:   1987VAN/TYB1063

Reaction:   CH2=CHCHO + 1,3-Cyclohexadiene → Bicyclo[2.2.2]oct-5-ene-2carboxaldehyde,(1α.2β,4α)-
Reaction order:   2
Temperature:   379 - 581 K
Pressure:  5.73E-2 - 0.27 bar
Rate expression:   1.0x10-15 [cm3/molecule s] e-87302 [J/mole]/RT
Uncertainty:   1.07000005
Bath gas:   1,3-Cyclohexadiene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
379 9.30E-28
400 3.98E-27
425 1.87E-26
450 7.36E-26
475 2.51E-25
500 7.59E-25
525 2.06E-24
550 5.12E-24
575 1.17E-23
581 1.42E-23