Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Wallington, T.J.; Neuman, D.M.; Kurylo, M.J.
Title:   Kinetics of the gas phase reaction of hydroxyl radicals with ethane, benzene and a series of halogenated benzenes over the temperature range 234-438 K
Journal:   Int. J. Chem. Kinet.
Volume:   19
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987WAL/NEU725

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1987WAL/NEU725   Benzene + ·OH → Adduct  234 - 296   1.30E-12              2
  1987WAL/NEU725   Benzene + ·OH → Products  393 - 438   3.25E-12       9229      2
  1987WAL/NEU725   C2H6 + ·OH·C2H5 + H2O  226 - 363   8.40E-12       8730   2.48E-13  2
  1987WAL/NEU725   Bromobenzene + ·OH → Products  234 - 353   9.00E-13           9.00E-13  2
  1987WAL/NEU725   Bromobenzene + ·OH → Products  438   2.19E-13              2
  1987WAL/NEU725   Chlorobenzene + ·OH → Products  234 - 296   6.91E-13              2
  1987WAL/NEU725   Chlorobenzene + ·OH → Products  393 - 438   2.01E-13              2
  1987WAL/NEU725   Hexafluorobenzene + ·OH → Products  234 - 438   1.30E-12       5072   1.68E-13  2
  1987WAL/NEU725   Fluorobenzene + ·OH → Products  234 - 303   6.19E-13           6.19E-13  2
  1987WAL/NEU725   Fluorobenzene + ·OH → Products  393 - 438   3.65E-13       2045      2
  1987WAL/NEU725   Iodobenzene + ·OH → Products  263 - 393   1.20E-13           1.20E-13  2

Search returned 11 records.