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Title: Investigation of reactions of Cr and Mo atoms in shock waves
Journal: Kinet. Catal.
Volume: 29
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988AKH/ZAS808
Reaction:
CO2 + Mo → CO + MoO
Reaction order:
2
Temperature:
1300 - 2900
K
Pressure: 0.40 - 0.67 bar
Rate expression:
1.05x10-10 [cm3/molecule s] e-81565 [±11391 J/mole]/RT
Uncertainty:
2.50999999
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1300 | 5.53E-14 |
| 1400 | 9.49E-14 |
| 1500 | 1.51E-13 |
| 1600 | 2.28E-13 |
| 1700 | 3.27E-13 |
| 1800 | 4.50E-13 |
| 1900 | 6.00E-13 |
| 2000 | 7.76E-13 |
| 2100 | 9.81E-13 |
| 2200 | 1.21E-12 |
| 2300 | 1.47E-12 |
| 2400 | 1.76E-12 |
| 2500 | 2.07E-12 |
| 2600 | 2.41E-12 |
| 2700 | 2.77E-12 |
| 2800 | 3.15E-12 |
| 2900 | 3.56E-12 |