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Accessibility information
Author(s):   Borrell, P.; Cobos, C.J.; Luther, K.
Title:   Falloff curve and specific rate constants for the reaction NO2 + NO2 N2O4
Journal:   J. Phys. Chem.
Volume:   92
Page(s):   4377 - 4384
Year:   1988
Reference type:   Journal article
Squib:   1988BOR/COB4377-4384

Reaction:   N2O4NO2 + NO2
Reaction order:   1
Temperature:   300 - 600 K
Pressure:  1.01 - 209 bar
Rate expression:   7.69x1015 [s-1] (T/298 K)-1.10 e-53711 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 3.40E6
325 1.63E7
350 6.21E7
375 1.97E8
400 5.39E8
425 1.30E9
450 2.85E9
475 5.71E9
500 1.07E10
525 1.87E10
550 3.11E10
575 4.93E10
600 7.51E10