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Accessibility information
Author(s):   Ghibaudi, E.; Colussi, A.J.
Title:   Kinetics and thermochemistry of the equilibrium 2 (acetylene) = vinylacetylene. Direct evidence against a chain mechanism
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988GHI/COL5839

Reaction:   Vinylacetylene + CH2C(·)CCCH
Reaction order:   1
Temperature:   1400 - 1500 K
Rate expression:   1.58x1015 [s-1] e-414061 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1400 5.63E-1
1425 1.05E0
1450 1.92E0
1475 3.43E0
1500 6.03E0